Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10570386 | Inorganic Chemistry Communications | 2010 | 5 Pages |
Abstract
In cis-(CO)-trans-(Cl)-[Ru(SRaaiNR)(CO)2Cl2] the SRaaiNR (1-alkyl-2-{(o-thioalkyl)phenylazo}imidazoles) acts as N(imidazole) (N), N(azo) (Nâ²) bidentate chelator while in trans-(Cl)-[Ru(SRaaiNR)(CO)Cl2] it is NNâ²S tridentate ligand. Electronic structure, spectral and redox properties of the complexes have been explained by the DFT and TDDFT computations.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
T.K. Mondal, P. Raghavaiah, A.K. Patra, C. Sinha,