Article ID Journal Published Year Pages File Type
10570386 Inorganic Chemistry Communications 2010 5 Pages PDF
Abstract
In cis-(CO)-trans-(Cl)-[Ru(SRaaiNR)(CO)2Cl2] the SRaaiNR (1-alkyl-2-{(o-thioalkyl)phenylazo}imidazoles) acts as N(imidazole) (N), N(azo) (N′) bidentate chelator while in trans-(Cl)-[Ru(SRaaiNR)(CO)Cl2] it is NN′S tridentate ligand. Electronic structure, spectral and redox properties of the complexes have been explained by the DFT and TDDFT computations.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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