| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10570445 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
The water-soluble complex [Ir(COD)(PTA)3]Cl (1, CODÂ =Â 1,5-cyclooctadiene, PTAÂ =Â 1,3,5-Triaza-7-phosphaadamantane) was prepared by the reaction of [IrCl(COD)]2 with PTA and is only one of the two [Ir(COD)P3]+ complexes to be structurally characterized as a square-pyramidal species. 1 and the related compounds, [IrCl(CO)(PTA)3] (2) and [Ir(CO)(PTA)4]Cl (3), were found to be active catalysts for the intramolecular hydroamination reaction in water.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Donald Alan Krogstad, Andrew J. DeBoer, William J. Ortmeier, Joseph W. Rudolf, Jason A. Halfen,