| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10570500 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
The reaction of aqueous solutions of magnesium dichloride with a 1:1 mixture of Na2CO3 and oxydiacetic acid or thiodiacetic acid affords [{Mg(oda)(H2O)2} · H2O]n (1) (oda=O(CH2COO)22-) and [Mg(tda)(H2O)3] · H2O (2) (tda=S(CH2COO)22-), respectively. Complex 1 is a one-dimensional polymer with a planar bridging oxydiacetate ligand, whereas 2 is a monomer containing a thiodiacetate ligand with a facial configuration.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Abdessamad Grirrane, Antonio Pastor, Eleuterio Álvarez, AgustÃn Galindo,