| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10570516 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
Oxidation reaction of the sterically constrained nonplanar Cu(II) 2,3,7,8,12,13,17,18-octaethyl-5,10,15,20-tetraphenylporphyrin complex ([Cu(OETPP)]) by Cu2+ was investigated in acetonitrile, and a slow electron self-exchange rate of the [Cu(OETPP)]+/0 couple as compared with the planar Cu(II) porphyrin complexes was ascribed to the significant deformation of the complex accompanied with the ligand oxidation.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Masahiko Inamo, Kaori Aoki, Noboru Ono, Hideo D. Takagi,