Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10570551 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
The reaction of 4â²-(4â²â²â²-pyridyl)-2,2â²:6â²,2â²â²-terpyridine (pyterpy) with copper(II) yields the novel mononuclear [Cu(pyterpy)2](PF6)2 complex. The crystal structure shows that the Cu(II) center is coordinated by the terpyridine domains of both pyterpy molecules, while the pyridyl tails remain uncoordinated. Intermolecular Ï-Ï stacking interactions between the cations in the crystal result in the formation of alternating 1-D linear channels which run in perpendicular directions.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Jesús Pitarch López, Werner Kraus, Günter Reck, Andreas Thünemann, Dirk G. Kurth,