Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571269 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
Nucleophilic attack of NaSiPr on [Cl2CC(H)-NCPh2}] (1) affords the 2-azabutadiene derivative [(i-PrS)2CC(H)-NCPh2] 2. In the case of cis-[(OC)4 Mo{(i-PrS)2CC(H)-NCPh2}] (3), coordination on Mo occurs through the imine nitrogen and a thioether group. Polydentate dithioether 2 acts as N,C,S-pincer ligand after orthometallation reaction with Pd(II) or Pt(II).
Related Topics
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Authors
Sandrine Jacquot-Rousseau, Abderrahim Khatyr, Gérard Schmitt, Michael Knorr, Marek M. Kubicki, Olivier Blacque,