Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571298 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
A manganese coordination polymer [Mn2(NTC)(H2O)2]n, where NTC is 1, 4, 5, 8-naphthalenetetracarboxylate anion, has been synthesized by slow diffusion of manganese chloride and H4 NTC. Mn(II) ions are bridged by one coordinated water and two carboxylate groups in syn-syn mode to form infinite chains, which are further cross-linked by the naphthalene spacers of the NTC to produce 3-D extended network with open-channels. An antiferromagnetic coupling interaction between adjacent manganese ions dominates the magnetic property of the compound.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Lan-Fen Chen, Jie Zhang, Li-Jun Song, Zhan-Feng Ju,