Article ID Journal Published Year Pages File Type
10571301 Inorganic Chemistry Communications 2005 6 Pages PDF
Abstract
The new binuclear complex [Cu(hfac)2(bpmu)]2 has been isolated by treatment of Cu(hfac)2 · H2O with bpmu. The single crystal X-ray structure reveals its dimeric nature and that the units are bonded through strong intra- and intermolecular OC(N-H)2⋯OC hydrogen bonds. The formation of the discrete species can be considered as the insertion of the bulky cis-{Cu(hfac)2} fragments into the prearranged hydrogen bonded pattern provided by the bpmu tecton through the OC(N-H)2⋯OC moieties.
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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