Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571310 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
A new Cu(II) chain compound, [Cu(1,10-phenanthroline)(μ-HPO4)(H2O)2]n1 has been synthesized hydrothermally and structurally characterized. The Cu(II) ion is tetragonally coordinated with a phen ligand and two aqua ligands in the equatorial plane and hydrogenphosphates as axial ligands, thereby forming a linear chain. The crystal lattice is formed from antiparallel chains, kept together by relatively strong phosphate-water H-bonds (intra- and intermolecular) and by interpenetrated stacking of the phen ligands with other chains. The magnetic susceptibilities are reported.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Sujittra Youngme, Pongthipun Phuengphai, Chaveng Pakawatchai, Gerard A. van Albada, Stefania Tanase, Ilpo Mutikainen, Urho Turpeinen, Jan Reedijk,