Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
10571312 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
The interaction of nickelocene with 3,6-di-tert-butyl-o-benzoquinone in toluene gives new 18-electron (η5-Cp)Ni(η3-cyclopentenyl type ligand) complex as the main product of hetero-Diels-Alder reaction. This process being carried out in THF solution is accompanied by ligands exchange and leads mainly to strong paramagnetic complex bis(3,6-di-tert-butyl-o-benzosemiquinonate)-bis(tetrahydrofuran)nickel(II).
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
A.V. Piskunov, G.K. Fukin, Yu.A. Kurskii, V.K. Cherkasov, G.A. Abakumov,