| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571318 | Inorganic Chemistry Communications | 2005 | 5 Pages |
Abstract
A novel heterospin system [MnIII(3-OMesalophen)(H2O)2]2[MnIII(3-OMesalophen)(H2O)] [WV(CN)8] · 2H2O consists of Mn6IIIW2V distinguishable structural and magnetic units due to the presence of cyano-bridged anionic MnIIIWV dimers and bis-μ-aqua-bridged dimers of [Mn(3-OMesalophen)(H2O)2]+ cations linked by H-bonds and Ï-Ï stacking interactions; it exhibits the strong antiferromagnetic coupling through the single cyano bridge and significant AF couplings through the hydrogen bonds.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Antiferromagnetic coupling through cyano-bridge and H-bonds in [MnIII(3-OMesalophen)(H2O)2]2[MnIII(3-OMesalophen)(H2O)] [WV(CN)8] · 2H2O](/preview/png/10571318.png "First Page Preview: Antiferromagnetic coupling through cyano-bridge and H-bonds in [MnIII(3-OMesalophen)(H2O)2]2[MnIII(3-OMesalophen)(H2O)] [WV(CN)8] · 2H2O")
Authors
PaweÅ PrzychodzeÅ, MichaÅ Rams, Carine Guyard-Duhayon, Barbara Sieklucka,