| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 10571331 | Inorganic Chemistry Communications | 2005 | 4 Pages |
Abstract
By reaction of (NH4)2[MoCl5(H2O)] with KNCO in hot pyridine, a mixture of mononuclear complexes containing mer-[Mo(NCO)3py3] and trans-[Mo(NCO)4py2]â species (py = pyridine) has been obtained. After the separation, the crystals of two complexes, mer-[Mo(NCO)3py3] · 2py and trans-(py2H)[Mo(NCO)4py2], have been prepared. The structures of both Mo(III) complexes were confirmed by X-ray analysis.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
![Syntheses and crystal structure of first octahedral d-metal complexes containing three and four isocyanato ligands, mer-[Mo(NCO)3py3] · 2py and trans-(py2H)[Mo(NCO)4py2]](/preview/png/10571331.png "First Page Preview: Syntheses and crystal structure of first octahedral d-metal complexes containing three and four isocyanato ligands, mer-[Mo(NCO)3py3] · 2py and trans-(py2H)[Mo(NCO)4py2]")
Authors
Nives Kitanovski, Amalija GolobiÄ, Boris Äeh,