Article ID Journal Published Year Pages File Type
1253951 Chinese Chemical Letters 2016 4 Pages PDF
Abstract

A highly enantioselective allylic substitution reaction of anthrones with aromatic or aliphatic allyl carbonates was realized by using iridium catalyst prepared from [Ir(COD)Cl]2 and BHPphos. Substituted 10-allylanthrones were obtained in excellent yields and with excellent enantioselectivity and regioselectivity (up to 98% yield, 99% ee) under mild conditions.

Graphical abstractIridium-catalyzed asymmetric intermolecular Friedel–Crafts type allylic substitution reaction of anthrones was developed, affording C10 substituted allylanthrones in good to excellent yields, regioselectivity and enantioselectivity.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Chemistry (General)
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