Fabrication of flower-like silver nanoparticles for surface-enhanced Raman scattering

The flower-like silver nanoparticles have been synthesized by reducing silver nitrate (AgNO3) with ascorbic acid (AA) as the reductant and polyvinyl pyrrolidone (PVP) as the capping agent under vigorous stirring. Such flower-like nanoparticles are aggregates of small nanoplates and nanorods. They were tested as substrates for the surface-enhanced Raman scattering (SERS), showing high sensitivity for detecting Rhodamine 6G (R6G) at a concentration as low as 10−7 mol/L. It has been found that replacing mechanical stirring with ultrasound sonication would drastically change the particle morphology, from flower-like nanoparticles to well-dispersed smaller nanoparticles. Furthermore, when trace amounts of NaCl were added into the reagents, well-dispersed Ag nanoparticles formed even in vigorous stirring. These phenomena can be explained with the diffusion and reactant supply during nucleation and growth of Ag nanoparticles.

Graphical abstractAggregation of Ag nanoparticles and dispersed irregular Ag nanoparticles synthesized by different mixing mode magnetic stirring and ultrasonic concussion, respectively. However, there is no distinct difference between their crystal structures.Figure optionsDownload full-size imageDownload as PowerPoint slide