Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1284172 | Journal of Power Sources | 2014 | 12 Pages |
•A two-step approach is demonstrated to fabricate a porous, ultrathin PANI-RGO electrode.•The thickness can be self-controlled by pH adjustment.•The well-designed PANI-RGO electrodes exhibit excellent photovoltatic performances.•The incorporation of RGO raises the transparency of PANI and photo harvest.•A universal approach is well-designed to fabricate PANI-RGO-based conductive thin films.
A powerful synthesis strategy is proposed for fabricating porous polyaniline-reduced graphene oxide (PANI-RGO) composites with transparency up to 80% and thickness from 300 to 1000 nm for the counter electrode (CE) of bifacial dye-sensitizing solar cells (DSSCs). The first step is to combine the in-situ positive charge transformation of graphene oxide (GO) through aniline (ANI) prepolymerization and the electrostatic adsorption of ANI oligomer-GO to effectively control the thickness of ultrathin PANI-GO films by adjusting pH of the polymerization media. In the second step, PANI-GO films are reduced with hydroiodic acid to simultaneously enhance the apparent redox activity for the I3−/I− couple and their electronic conductivity. Incorporating the RGO increases the transparency of PANI and facilitates the light-harvesting from the rear side. A DSSC assembled with such a transparent PANI-RGO CE exhibits an excellent efficiency of 7.84%, comparable to 8.19% for a semi-transparent Pt-based DSSC. The high light-harvesting ability of PANI-RGO enhances the efficiency retention between rear- and front-illumination modes to 76.7%, compared with 69.1% for a PANI-based DSSC. The higher retention reduces the power-to-weight ratio and the total cost of bifacial DSSCs, which is also promising in other applications, such as windows, power generators, and panel screens.
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