Ball-milling preparation of one-dimensional Co–carbon nanotube and Co–carbon nanofiber core/shell nanocomposites with high electrochemical hydrogen storage ability

•1D CNT (CNF)/Co nanocomposites were synthesized by a ball-milling method.•Co shell with diameter of 4 nm has been successfully coated on CNT.•The composites exhibited good hydrogen storage performance.

Owing to the special honeycomb structures and excellent electrical characters of carbon nanotube (CNT) and carbon nanofiber (CNF), they are extensively considered as ideal cornerstones for hydrogen storage materials. Herein, metal cobalt has been uniformly coated on CNT's and CNF's surfaces in nanoscale through a simple ball milling process. Accordingly their X-ray diffraction, scanning electron microscope and transmission electron microscopy measurements clarify the satisfying composite structures. And their electrochemical experimental results demonstrate that the as-obtained CNT/Co and CNF/Co composites have excellent electrochemical hydrogen storage reversibility and considerably high storage capacities of 717.3 mAh g−1 (2.62 wt% hydrogen) and 739.4 mAh g−1 (2.70 wt% hydrogen) under room temperature and ambient pressure, which are much higher than the capacities of individual CNT (29.9 mAh g−1, 0.11 wt% hydrogen) and CNF (49.0 mAh g−1, 0.18 wt% hydrogen) measured in this work. Furthermore their hydrogen storage processes and the mechanism have also been investigated, in which the quasi-reversible CNT (CNF)/Co ↔ CNT (CNF)/Co–Hx reaction is the dominant cycle process.

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