Article ID Journal Published Year Pages File Type
1285992 Journal of Power Sources 2007 4 Pages PDF
Abstract

Cation (Mg and Al)-substituted spinel were synthesized using metal oxide precursor by co-precipitation method. XRD revealed that the prepared substituted spinel has spinel structure with Fd3m space group. In order to compensate the decreased initial capacity of cation-substituted spinel, partial anion (F) substitution was also carried out. The cycling performance of all the substituted spinel was improved, compared to the Li1.05Mn1.95O4 at 55 °C. Li1.05Al0.1Mn1.85O3.95F0.05 showed better capacity retention than the other substituted spinels. Both cation and anion substitution appeared to be effective for improving the cycling performance of spinel material at elevated temperature.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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