Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1287601 | Journal of Power Sources | 2006 | 7 Pages |
Abstract
Rate equation of LiFePO4 formation via solid-state reaction has been studied by using a model system: Li(CH3COO) + FePO4 in a reducing atmosphere. Kinetic data were acquired by using in-situ synchrotron X-ray diffraction technique, and the analysis was based on a non-isothermal methodology, which shows that the reaction rate is well described by the rate-equation: [F0.7/(1 â F)0.7] = 1.56 Ã 1011 exp(â24,100/T)t, where F is the fractional conversion to LiFePO4, T, the calcination temperature (K), and t is the calcination time (min). The equation indicates that the formation of LiFePO4 is intrinsically a fast reaction: 95% conversion can be achieved between 550 and 600 °C in a few hours. Nevertheless, the reaction could be significantly hindered if gas-phase diffusion processes of reactant/product species become rate-limiting, and the gas-flow pattern relative to the powder bed during synthesis thus has a decisive effect on the reaction rate in large-scale synthesis. Single-phased, nanocrystalline LiFePO4 powder having an average crystal size of 35 nm can be synthesized by calcination using flow-through configuration at 600 °C in merely 2 h, and the powder exhibits a capacity of â¼140 mAh gâ1.
Related Topics
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Authors
Hao-Hsun Chang, Chun-Chih Chang, Hung-Chun Wu, Zheng-Zhao Guo, Mo-Hua Yang, Yung-Ping Chiang, Hwo-Shuenn Sheu, Nae-Lih Wu,