| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1287962 | Journal of Power Sources | 2013 | 5 Pages |
The electrochemical properties of Na4Co3(PO4)2P2O7 as a positive electrode for sodium-ion batteries were characterized by a cyclic voltammetry technique and galvanostatic charge/discharge tests. Interestingly, Na4Co3(PO4)2P2O7 has the multi redox couples in the highest potential region between 4.1 V and 4.7 V among ever reported sodium storage materials and can deliver the reversible capacity of ca. 95 mAhg−1, corresponding to ca. 2.2 Na+ extraction and insertion in Na4Co3(PO4)2P2O7, at the current density of 34 mAg−1 (0.2 C). Na4Co3(PO4)2P2O7 also exhibits the high rate capabilities and has a small polarization in the charge–discharge profile even at the high current densities of 4.25 Ag−1 (25 C), resulting in high energy efficiency of the battery. These performances indicate Na4Co3(PO4)2P2O7 can be one of the good candidates for a positive electrode material of sodium-ion batteries.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A novel storage material Na4Co3(PO4)2P2O7 was prepared by a typical sol–gel method. ► Multistep redox behavior was confirmed in the high potential region between 4.1 V and 4.7 V vs. Na+/Na. ► The reversible capacity of Na4Co3(PO4)2P2O7 reaches ca. 95 mAhg−1. ► Na4Co3(PO4)2P2O7 exhibits the compatibility of high operating potential and high rate capabilities.
