Article ID Journal Published Year Pages File Type
1289603 Journal of Power Sources 2011 4 Pages PDF
Abstract
Reduced graphene sheets (RGSs) were prepared via chemical reduction of graphite oxide and their morphology was characterized by atomic force microscopy. The electrochemical reduction of oxygen (O2) with RGSs was studied by cyclic, rotating disk electrode, and rotating ring-disk electrode voltammetry using the RGSs-modified glassy carbon (RGSs/GC) electrode in 3.5% NaCl solution. The results show that O2 reduction undergoes three steps at the RGSs/GC electrode: electrochemical reduction of O2 to H2O2 mediated by quinone-like groups on the RGSs surface, a direct 2-electron reduction of O2, and reduction of the H2O2 produced to H2O. The modification of RGSs results in an obvious positive shift of the peak potential and a larger current density. The kinetics study shows that the number of electrons transferred for O2 reduction can reach to 3.0 at potentials of the first reduction step, indicating RGSs can effectively catalyze the disproportionation of H2O2. Such catalytic activity of RGSs enables a 4-electron reduction of O2 at a relatively low overpotential in neutral media. RGSs are a potential electrode material for microbial fuel cells.
Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
Authors
, , , ,