Article ID Journal Published Year Pages File Type
1290529 Journal of Power Sources 2010 5 Pages PDF
Abstract

LixMnO2 (x = 0.302) was synthesized by chemical lithiation, using a formaldehyde reducing agent and a LiOH lithium source in an aqueous media. The electrochemical properties and structural stability of the product were characterized by X-ray diffraction and charge–discharge measurements. The chemically lithiated LixMnO2 had a first charge and discharge capacity of 86.2 and 265 mAh/g, respectively, with good cycling behavior. Based on the electrochemical results of the first charge, a two-step mechanism of LixMnO2 lithiation is proposed. γ-MnO2 is first oxidized by formaldehyde, and then Li diffuses into the γ-MnO2 lattice.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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