Article ID Journal Published Year Pages File Type
1291798 Journal of Power Sources 2016 7 Pages PDF
Abstract

•Aqueous Na-Zn hybrid batteries were assembled based on NiHCF and Zn electrodes.•The aqueous battery showed an average operating voltage of 1.5 V.•The aqueous Na-Zn battery exhibited high energy density (62.9 Wh kg−1).

Rechargeable aqueous batteries are very attractive as a promising alternative energy storage system, although their reversible capacity is typically limited. A new rechargeable Na-Zn hybrid aqueous battery with nickel hexacyanoferrate (NiHCF) cathode and the nanostructured zinc anode is fabricated. The rational combination of two materials with mild aqueous electrolyte renders the devices with an average operating voltage close to 1.5 V, higher specific capacity of 76.2 mAh g−1, and a good cycling stability with 81% capacity retention for 1000 cycles. These remarkable features can provide guidance for the development of rechargeable batteries from the naturally abundant electrode materials with neutral aqueous electrolytes.

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Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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