Article ID Journal Published Year Pages File Type
1292440 Journal of Power Sources 2006 5 Pages PDF
Abstract

Li4+XTi5O12 (X > 0) negative active material has been successfully synthesized by a new chemical method for Li-doping with the catalytic function of naphthalene in Li-organic complex solution of butylmethylether (BME) or dimethoxyethane (DME) solvent. The Li-doping reaction rate constant in BME was found to be greater than that of the case of DME and its value was 5.10 and 2.78 × 10−4 S−1/2, respectively, by the calculation from the slope of distinct straight line in the relationship between ln(1/1 − Y  ) and t, where Y is molar fraction of Li-doping materials of Li7Ti5O12.

Related Topics
Physical Sciences and Engineering Chemistry Electrochemistry
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