| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301307 | Inorganic Chemistry Communications | 2015 | 4 Pages |
•Combination of 1,3-di-(1,2,4-triazole-4-yl)benzene ligand and 1,3,5-benzene-tricarboxylic acid as the co-ligands•Unique 3-D open framework with intersecting channels•Two trinuclear Co(II) secondary building units•Antiferromagnetic interactions between the Co(II) cations
A new Co(II) coordination polymer, namely [Co6(btc)4(dtb)2(H2O)3]n (1) (H3btc = 1,3,5-benzenetricarboxylic acid, dtb = 1,3-di-(1,2,4-triazole-4-yl)benzene), has been synthesized by combining the mixed ligands of H3btc and dtb with Co(Ac)2·4H2O under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that 1 feature a 3D open framework with intersecting channels based on Co-btc3 − layers and btc3 − and dtb pillars. The magnetic property of the complex has also been investigated at room temperature.
Graphical abstractA new Co(II) coordination polymer, namely [Co6(btc)4(dtb)2(H2O)3]n (1) (H3btc = 1,3,5-benzenetricarboxylic acid, dtb = 1,3-di-(1,2,4-triazole-4-yl)benzene), has been synthesized. Compound 1 features a 3-D open framework with intersecting channels based on Co-btc3 − layers and btc3 − and dtb pillars.Figure optionsDownload full-size imageDownload as PowerPoint slide
