Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1301476 | Inorganic Chemistry Communications | 2015 | 4 Pages |
•A novel axially substituted porphyrin derivative was prepared.•The molecular structure of the complex was determined by X-ray diffraction study.•Z-scan measurement shows improved nonlinear optics for this complex.
A novel zinc porphyrin (ZnTPP) derivative bearing an E-stilbazole chromophore in the axial position (ZnTPPL) was designed and prepared. Z-scan studies reveal that this complex exhibits improved nonlinear optical absorption and refraction in comparison with ZnTPP. In addition, the molecular structure of the complex was determined by X-ray diffraction study.
Graphical abstractA novel zinc porphyrin (ZnTPP) derivative bearing an E-stilbazole chromophore in the axial position (ZnTPPL) was designed and prepared. Z-scan studies reveal that this complex exhibits improved nonlinear optical properties compared to ZnTPP.Figure optionsDownload full-size imageDownload as PowerPoint slide