Article ID Journal Published Year Pages File Type
1301476 Inorganic Chemistry Communications 2015 4 Pages PDF
Abstract

•A novel axially substituted porphyrin derivative was prepared.•The molecular structure of the complex was determined by X-ray diffraction study.•Z-scan measurement shows improved nonlinear optics for this complex.

A novel zinc porphyrin (ZnTPP) derivative bearing an E-stilbazole chromophore in the axial position (ZnTPPL) was designed and prepared. Z-scan studies reveal that this complex exhibits improved nonlinear optical absorption and refraction in comparison with ZnTPP. In addition, the molecular structure of the complex was determined by X-ray diffraction study.

Graphical abstractA novel zinc porphyrin (ZnTPP) derivative bearing an E-stilbazole chromophore in the axial position (ZnTPPL) was designed and prepared. Z-scan studies reveal that this complex exhibits improved nonlinear optical properties compared to ZnTPP.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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