| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301517 | Inorganic Chemistry Communications | 2015 | 4 Pages |
•A new charge-transfer Cu-MOF has been synthesized and characterized.•Complex 1 has a good thermal stability.•Complex 1 exhibits intriguing solvent-dependent luminescence behaviors.•The luminescent origin of 1 is confirmed via the in-depth computations.
Herein we report the first charge-transfer metal–organic framework with open Cu(I)-sites, which exhibits intriguing solvent-dependent luminescence behaviors. An extended analysis of experimental and computational result indicates that strong metal–solvent bonding interaction plays a dominant role in the sensing of various solvents.
Graphical abstractA new charge-transfer metal–organic framework with open Cu(I)-sites has been obtained, which exhibits intriguing solvent-dependent luminescence behaviors. An extended analysis of experimental and computational result indicates that strong metal–solvent bonding interaction plays a dominant role in the sensing of various solvents.Figure optionsDownload full-size imageDownload as PowerPoint slide
