| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301595 | Inorganic Chemistry Communications | 2016 | 4 Pages |
•A new POM-based CuI coordination polymers have been hydrothermally synthesized.•Compound 1 displays high heat stability, acid and alkali resistance.•It shows efficient visible-light-driven photocatalytic activities in the degradation of organic dyes.
A new coordination polymer (CP), [(PW12O40)2CuI6(trz)6]·H2O (1), has been prepared by hydrothermal method. Six Cu(I) ions are bridged by six trz molecules and six surface oxygen atoms of PW12 to generate a wheel-type CuI6 cluster, and each CuI6 cluster was capped with two PW12 anions to form a dumbbell-like second building block (SBB). 1 can remain intact in solution with pH range from 1 to 10, boiling water and boiling organic solvents, which shows the high heat stability, acid and alkali resistance. It also shows efficient visible-light-driven photocatalytic activities in the degradation of organic dyes.
Graphical abstractA new 3D POM-based Cu(I) coordination polymer has been successfully prepared by in-situ hydrothermal reaction. Compound 1 shows remarkably stability and efficient photocatalytic activities in the degradation of organic dyes.Figure optionsDownload full-size imageDownload as PowerPoint slide
