| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301607 | Inorganic Chemistry Communications | 2016 | 5 Pages |
•Cl−, OH−, and I−μ2-bridged dinuclear complexes•non-centrosymmetric dinuclear complexes•non-linear optical, and ferroelectric and magnetic properties
2-[(S)-4-isopropyl-2-oxazolyl]quinoline (L1) and 2-[(S)-4-phenyl − 2-oxazolyl]quinoline (L2) react with manganese, cobalt and copper salts to yield four new complexes: [Mn2(L1)2]Cl2 (1), {[Co(L1)2]2(OH)}(ClO4)3 (2), [Cu2I2(L1)2] (3), and {[Cu(L2)2]2(OH)}(BF4)3·H2O (4), which were fully characterized by single-crystal and powder X-ray diffraction, IR, elemental and thermogravimetric analyses. Complexes 1–4 all show dinuclear structure. Two metal ions are bridged by Cl− in 1, by OH– in 2 and 4, and by I− in 3. Moreover, non-linear optical, and ferroelectric and magnetic properties have been investigated.
Graphical abstract2-[(S)-4-isopropyl-2-oxazolyl]quinoline (L1) and 2-[(S)-4-phenyl − 2-oxazolyl]quinoline (L2) react with manganese, cobalt and copper salts to yield four new complexes. Non-linear optical, and ferroelectric and magnetic properties have been investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide
