Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1301729 | Inorganic Chemistry Communications | 2016 | 4 Pages |
•This is the first combination of light-weight frameworks with nucleobase ligands.•The unprecedented μ4-bridging model of hypoxanthine nucleobase greatly enriches its coordination applications in metal-biomolecule frameworks.•The “light” metal supertetrahedral cluster that will display significant potentials in constructing “light” zeolitic materials.
Two “light” zeolitic cluster-organic frameworks are constructed from supertetrahedral pentanuclear lithium cluster and unprecedented μ4-hypoxanthine nucleobase.
Graphical abstractThe combination of supertetrahedral pentanuclear lithium cluster and unprecedented μ4-hypoxanthine nucleobase lead to the formation of “light” zeolitic cluster-organic frameworks.Figure optionsDownload full-size imageDownload as PowerPoint slide