| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301735 | Inorganic Chemistry Communications | 2016 | 4 Pages |
•Dinuclear Ag(I) complexes bearing the P ∩ N ligand 2-diphenylphosphino-6-methylpyridine have been prepared.•The complex have the generic formula [Ag2(P ∩ N)3(NCR)](BF4)2 (R = Me, Et, Ph).•The crystal structures were determined.•The nitrile ligands can be easily exchanged by re-crystallisation in the respective organic nitrile.
We have prepared three silver(I) complexes of the type [Ag2(P ∩ N)3(NCR)](BF4)2 with (R = Me, Et, Ph). The crystal structures of the complexes were determined. The nitrile ligands can be easily exchanged by re-crystallisation in the respective nitrile. The luminescence properties were also investigated.
Graphical abstractWe have prepared three silver(I) complexes of the type [Ag2(P ∩ N)3(NCR)](BF4)2 with (R = Me, Et, Ph). The crystal structures of the complexes were determined. The nitrile ligands can be easily exchanged by re-crystallisation in the respective nitrile. The luminescence properties were also investigated.Figure optionsDownload full-size imageDownload as PowerPoint slide
