| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301811 | Inorganic Chemistry Communications | 2013 | 5 Pages |
•[Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O were sythesized using hydrothermal method.•The effect of pH of reaction media is studied.•Purple crystals were analysed using IR, UV and X-ray diffraction.•Molecule extends in 3D through hydrogen bonding.
A novel inorganic–organic hybrid molecule, [Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O (1), has been hydrothermally synthesized and characterized by IR spectra, TG and single crystal X-ray diffraction analyses. Structural analysis reveals that the novel compound 1 composed of two Kegging polyoxoanion connected with Cu complex fragment forming a big molecule that extends in 3D via hydrogen bonding.
Graphical abstractStructure of [Cu(4,4′bipyH)3(4,4bipy)][HPW12O40]2.12H2O consists of two Kegging polyoxoanion connected with Cu complex fragment forming a big molecule that extends in 3D via hydrogen bonding.Figure optionsDownload full-size imageDownload as PowerPoint slide
