Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1301813 | Inorganic Chemistry Communications | 2013 | 4 Pages |
•A 3D ten-connected self-penetrating network is formed•The pentacobalt(II) clusters act as SBU•Ile-364345362 network is indicated•Antiferromagnetic interactions between the Co(II) cations are revealed
A 3D ten-connected self-penetrating network based on the pentacobalt(II) clusters, [Co5(1,4-ndc)4(OH)2(1,3-bix)2]n (1) (1,4-H2ndc = 1,4-naphthalenedicarboxylic acid; 1,3-bix = 1,3-bis(imidazol-1-ylmethyl)benzene), is synthesized and characterized. Topological analysis indicates that it has ile-364345362 network. The magnetic data reveals the dominant antiferromagnetic interactions between the Co(II) cations.
Graphical abstractA 3D ten-connected self-penetrating network based on the pentacobalt(II) clusters is synthesized and characterized, Topological analysis indicates that it has ile-364345362 network. The magnetic data reveals the dominant antiferromagnetic interactions between the Co(II) cations.Figure optionsDownload full-size imageDownload as PowerPoint slide