| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301870 | Inorganic Chemistry Communications | 2013 | 4 Pages |
•An Fe(II)-cyclotriphosphazene and its polyphosphazene analogue are synthesised.•The Fe(II)-cyclotriphosphazene is high spin at all measurable temperatures.•Its polyphosphazene analogue remains low spin.
Mössbauer and electronic absorbance spectroscopy along with variable temperature magnetic moment measurements demonstrate that a cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety (1) and its polyphosphazene analogue (2) differ significantly in magnetic behaviour.
Graphical abstractA cyclotriphosphazene substituted with an iron(II)-bis-2,6-di(1H-pyrazoly-yl)pyridine moiety and its polyphosphazene analogue differ significantly in magnetic behaviour.Figure optionsDownload full-size imageDownload as PowerPoint slide
