| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301988 | Inorganic Chemistry Communications | 2013 | 4 Pages |
Two new complexes, [CoL2]2[Co(CH3OH)4] (1), and [Ni2L2(CH3OH)2]n (2) (H2L = 2-(((2-hydroxynaphthalen-1-yl)methylene)amino)acetic acid), have been synthesized and structurally characterized. Single-crystal X-ray analysis reveals that complex 1 is linear trinuclear mixed valence cobalt complex, while complex 2 is a 2D complex by double naphtholate bridged and syn–anti carboxylate bridged. Magnetic susceptibility measurements indicate that 1 shows mononuclear CoII behavior whereas 2 exhibits an antiferromagnetism behavior.
Graphical abstractTwo new complexes, [CoL2]2[Co(CH3OH)4] (1), and [Ni2L2(CH3OH)2]n (2) (H2L = 2-(((2-hydroxynaphthalen-1-yl)methylene)amino)acetic acid), were successfully synthesized and magnetic properties studied.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A linear trunuclear cobalt 1 and a 2D nickel complex 2 have been characterized. ► The flexible ligands have two coordination modes in the complexes. ► The magnetic properties of two complexes have been investigated.
