| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1301999 | Inorganic Chemistry Communications | 2013 | 4 Pages |
The 8-caffeinyl cobalt(І) complex (C8-caffeinyl)Co(PMe3)4 (1) was obtained by reaction of caffeine with cobalt(I) complex CoMe(PMe3)4 via CH bond activation with the escape of methane. The reaction of 1 with arylbromide afforded cobalt(II) complex (C8-caffeinyl)Co(PMe3)3Br (2) and the C,C-coupling products 8-aryl caffeine (3 and 4), 8-phenyl caffeine and 8-(2′-pyridinayl)caffeine. The crystal structures of complexes 1 and 2 were determined by X-ray diffraction.
Graphical abstractThe 8-caffeinyl cobalt(І) complex (C8-caffeinyl)Co(PMe3)4 (1) was obtained by reaction of caffeine with cobalt(I) complex CoMe(PMe3)4 via CH bond activation with the escape of methane. The reaction of 1 with aryl bromide afforded cobalt(II) complex (C8-caffeinyl)Co(PMe3)3Br (2) and the C,C-coupling products 3 and 4 (8-aryl caffeine).Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Synthesis and characterization of an 8-caffeinyl cobalt(І) complex ► CH bond activation ► C,C-coupling reaction ► Cobalt complex with trimethylphosphine as supporting ligand
