| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302030 | Inorganic Chemistry Communications | 2013 | 5 Pages |
A 1D polyoxometalate chain has been constructed from a {Mo16Ni16P24} cluster linked by two {NiO6} edge-shared octahedrons. This chained molybdenum nickel phosphate, Na2[Ni(H2O)8][Ni2(H2O)6][(Mo16O32)Ni16(OH)8(H2PO4)4(HPO4)16(PO4)4(H2O)8]·14H2O (1), crystallizes under hydrothermal reaction and in the monoclinic space group C2/m. In the chain of 1, another {NiO8} polyhedron is capsulated in the {Mo16Ni16P24} wheel. Magnetism analysis shows that there are antiferromagnetic interactions in 1.
Graphical abstractA 1D polyoxometalate chain Na2[Ni(H2O)8][Ni2(H2O)6][(Mo16O32)Ni16(OH)8(H2PO4)4(HPO4)16(PO4)4(H2O)8]·14H2O constructed from a {Mo16Ni16P24} cluster has been synthesized under hydrothermal conditions. The magnetic studies reveal that antiferromagnetic interactions exist in the chain.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A 1D polyoxometalate chain has been constructed from a {Mo16Ni16P24} cluster. ► In the chain, another {NiO8} polyhedron is capsulated in the {Mo16Ni16P24} wheel. ► The magnetic properties of the reported compound have been investigated.
