| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302032 | Inorganic Chemistry Communications | 2013 | 4 Pages |
The structural aspects and magnetic properties of a novel five-coordinated copper(II) coordination polymer derived from a carboxylate tethered naphthalimide ligand, namely 5-(1,3-dioxo-1H, 3H-benzo[de]isoquinolin-2-yl)-isophthalic acid are presented. The coordination polymer having monodentate carboxylate groups connecting the copper ions to form a spiral duplex structure shows anti-ferromagnetic property.
Graphical abstractThe role of coordinated water molecules in a novel five-coordinated copper(II) coordination polymer having spiral duplex structure showing anti-ferromagnetic property is discussed.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► A naphthalimide bearing coordination polymer of copper(II) having spiral duplex structure is presented. ► The orientations of the aqua-ligands in the chains are responsible for the formation of duplex structure. ► The penta-coordinated coordination polymer is weakly antiferromagnetic.
