| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302092 | Inorganic Chemistry Communications | 2011 | 4 Pages |
A tetrameric spin crossover (SCO) FeII complex was synthesized, and the structure and magnetic properties were studied. The tetrameric structure is constructed by four imidazole···Cl− hydrogen bonds centered at one Cl− ion. The compound showed an incomplete gradual SCO behavior due to intra-cluster “anticooperative-like“ interaction.
Graphical abstractA tetrameric spin crossover (SCO) FeII complex was synthesized, and the structure and magnetic properties were studied. The tetrameric structure was constructed by four imidazole·Cl− hydrogen bonds centered at one Cl− ion. The compound showed an incomplete gradual SCO behavior due to intra-cluster “anticooperative-like” interactions.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch Highlights► A tetrameric spin crossover (SCO) FeII complex was synthesized. ► The structure and magnetic properties were studied. ► The tetrameric structure is constructed by four imidazole···Cl- hydrogen bonds. ► The compound showed an gradual SCO due to intra-cluster “anticooperative-like“ interaction.
