| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302104 | Inorganic Chemistry Communications | 2011 | 4 Pages |
Abstract
The reaction of [Mo(CN)8]3− with Dy3+ in DMF solvent leads to a new binuclear complex, [Mo(CN)8Dy(DMF)4(H2O)3]·H2O (1) (DMF = N,N′-dimethylformamide). Magnetic measurements confirm that 1 presents probably a ferromagnetic interaction between the binuclear complexes.
Graphical abstractConstruct a binuclear MoV–DyIII complex, in which the coordination sphere of Dy and Mo atoms lie in a slightly distorted trigonal dodecahedron geometry and linked by cyanide group.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch Highlights► Magnetic analysis. ► The magnetic anisotropy of DyIII ion. ► The progressive depopulation of excited Stark sublevels of DyIII ion.
Related Topics
Physical Sciences and Engineering
Chemistry
Inorganic Chemistry
Authors
Shi Ren, Shu-Lin Ma, Gong-Feng Xu, Bin Gu, Yue Ma, Qing-Lun Wang, Dai-Zheng Liao,