Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1302116 | Inorganic Chemistry Communications | 2011 | 4 Pages |
A flexible coordination polymer 1 with interdigitated structure has been synthesized from 4,4′-(hexafluoroisopropylidene)bis(benzoic acid) ligand and Cd2+ salt, whose 3D interdigitated framework displays novel 5-connected BN topology involving both covalent and strong hydrogen bonds. The luminescent properties of 1 are discussed.
Graphical abstractA flexible 3D interdigitated coordination framework was mutually assembled from 2D layer with strong hydrogen bonds, which gives novel 5-connected BN topology.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch Highlights► The coordination polymer displays interdigitated structure. ► The 3D framework exhibits 5-connected BN topology involving both covalent and hydrogen bonds. ► The luminescent and thermol properties of compound are investigated.