Design and construction of self-penetrating coordination frameworks

Self-penetrating coordination networks have recently been demonstrated as an important family of coordination polymers with new topologies and properties. However, the design and control of self-penetrating systems is still an enthralling challenge. In this review, we present the topological types of self-penetrating coordination networks, mainly with single-connectivity, and summarize their designing and constructing strategy.

Graphical AbstractThis review discusses the recent development on the design and construction of self-penetrating coordination nets showing various topological types, mainly with single-fold connectivity.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch Highlights►The topological types of self-penetrating coordination networks have been summarized. ►The general tactics for their rational design have been proposed. ►In such area, the next phase of growth has been shown.