Synthesis, crystal structure and photoluminescence of a new Cd(II) coordination polymer with unusual geometry

A new coordination polymer 1 [CdL2(NO3)2]n (L: 3, 6-di-(1, 2, 4-triazole-1-yl)-N-ethylcarbazole) has been synthesized by self-assembly reaction and characterized by elemental analysis and IR spectroscopy. The single-crystal X-ray diffraction shows that the [CdL2(NO3)2]n crystallizes in the monoclinic system and C2/m space group and the Cd(II) atom is four-coordinated. The coordination polyhedron can be described as a rectangle which is rather infrequent. The coordination bonds, hydrogen bonds and π–π interactions shaped the 3D network structure. A possible formation mechanism was discussed. The optical property was also studied.

Graphical AbstractThe [CdL2(NO3)2]n crystallizes in the monoclinic system and C2/m space group and the Cd(II) atom is four-coordinated. The coordination polyhedron can be described as a rectangle which is rather infrequent. The coordination bonds, hydrogen bonds and π–π interactions shaped the 3D network structure. The solid-state fluorescent property was investigated at room temperature. Figure optionsDownload full-size imageDownload as PowerPoint slide