Article ID Journal Published Year Pages File Type
1302283 Inorganic Chemistry Communications 2010 5 Pages PDF
Abstract

Three coordination polymers containing 2-(2-pyridyl)benzimidazole (PyHBIm) ligand, namely {[Zn3(PyBIm)3(PyHBIm)2(tma)(H2O)]•H2O}n (1), [Zn(PyHBIm)(oba)]n (2), [Cd(PyHBIm)(oba)]n (3), (tma = trimesate, oba = 4,4′-oxybis-(benzoate)), have been prepared through hydrothermal reaction. Compound 1 exhibits one-dimensional (1D) helical structure. However, compounds 2 and 3 display 1D meso-helical structure. These 1D structures are further assembled into three-dimensional (3D) networks through aromatic π–π stacking interactions and hydrogen bonding interactions. Moreover they all exhibit strong photoluminescence at room temperature and may be good candidates for potential luminescence materials.

Graphical AbstractThree new coordination polymers containing 2-(2-pyridyl)benzimidazole (PyHBIm) ligand, namely {[Zn3(PyBIm)3(PyHBIm)2(tma)(H2O)]•H2O}n (1), [Zn(PyHBIm)(oba)]n (2), [Cd(PyHBIm)(oba)]n (3), (tma = trimesate, oba = 4,4′-oxybis(benzoate)), have been prepared through hydrothermal reaction. They exhibit two different kinds of 1D helical structures. Compound 1 exhibits 1D helical structure. However, compounds 2 and 3 display 1D meso-helical structure.Figure optionsDownload full-size imageDownload as PowerPoint slide

Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
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