Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1302318 | Inorganic Chemistry Communications | 2012 | 4 Pages |
Treatment of a mixture of isomeric N-ethyl-4(5)-nitro-1,2,3-triazoles with copper(II) chloride or copper(II) perchlorate was found to yield crystalline complexes with 1-ethyl-5-nitro-1,2,3-triazole (entz), namely [Cu(entz)2Cl2] or [Cu(entz)4(H2O)2](ClO4)2, respectively. The obtained complexes, being the rare examples of coordination compounds of vicinal nitrotriazoles, have been characterized by X-ray diffraction and thermal methods. Both compounds present mononuclear complexes with entz сoordinating through N3 atom of heterocycle. The complexes are readily decomposed under action of aqueous ammonia generating pure 1-ethyl-5-nitro-1,2,3-triazole with high yield. Succession of complexation and decomplexation reactions was shown to be a simple procedure for isolation of 1-ethyl-5-nitro-1,2,3-triazole from isomeric mixtures formed under alkylation of 4-nitro-1,2,3-triazole.
Graphical abstractPure crystalline complexes of 1-ethyl-5-nitro-1,2,3-triazole were formed under treatment of a mixture of isomeric N-ethyl-4(5)-nitro-1,2,3-triazoles with copper(II) salts.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Copper(II) salts react selectively with 1-ethyl-5-nitro-1,2,3-triazole. ► New examples of rare complexes with vicinal nitrotriazoles. ► 1-Ethyl-5-nitro-1,2,3-triazole coordinates through N3 atom of heterocycle. ► Complexes are decomposed under action of aqueous ammonia generating pure ligand. ► Selective complexation–decomplexation technique for separation of isomeric azoles.