Article ID Journal Published Year Pages File Type
1302368 Inorganic Chemistry Communications 2008 4 Pages PDF
Abstract
Reaction of (PCP)i-PrPdCl and K-Selectride® solution does not yield a simple (PCP)i-PrPdH species, but rather an adduct containing K(sec-Bu3BH). This adduct has been characterized by X-ray crystallography, revealing that the tri-coordinate K+ ion is bound only to hydrides. This [H3K]+ bonding mode for K+ ions was previously unknown.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Inorganic Chemistry
Preview
An unprecedented bonding mode for potassium within a PCP-pincer palladium hydride-K-Selectride® complex
Authors
, , , ,