| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302391 | Inorganic Chemistry Communications | 2012 | 4 Pages |
Two lanthanide/zinc coordination polymers, [Zn2Pr(H2O)4(OH)(bipy)(IMDC)2]·bipy·2H2O (1), and [Pr(phen)(HDTIM)(NO3)(H2O)]·H2O (2), based on 2H-imidazole-4,5-dicarboxylic acid (H3IMDC) and 4,5-di(1H-tetrazol-5-yl)-2H-imidazole (H3DTIM) ligands have been synthesized. Both ligands were in situ generated from the same precursor, 2H-imidazole-4,5-dicarbonitrile (HIMDN), by control of the reaction condition.
Graphical abstractTwo novel lanthanide/zinc coordination polymers with 1D chain and 2D bilayer framework based on 2H-imidazole-4,5-dicarboxylic acid (H3IMDC) and 4,5-di(1H-tetrazol-5-yl)-2H-imidazole (H3DTIM) ligands have been synthesized.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► We synthesized two novel lanthanide/zinc coordination polymers with 1D chain and 2D bilayer framework. ► Complex 1 is a heterometallic two-dimensional coordination polymer templated by 4,4′-bipy molecules. ► Complex 2 is a 1D lanthanide coordination polymer.
