| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302441 | Inorganic Chemistry Communications | 2008 | 6 Pages |
Abstract
Two novel zinc(II) coordination complexes [Zn2(L)(CO3)]Br2 · 7H2O (1) and [Zn2(L)(CO3)]Br2 · 0.5CH3COCH3 · 5H2O (2) with 1D chain structure linked by carbonate anions were obtained by reactions of new macrocyclic ligand 3, 6, 9, 12, 20, 23, 26, 29-octaazatricyclo[29.3.1.114,18]hexatriaconta-1(34), 14, 16, 18(36), 31(35), 32-hexaene (L) with zinc salt at an initial pH of ca. 9.5. The results show that carbon dioxide from air was absorbed and converted to carbonate anion during the formation of 1 and 2.
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Authors
Zhao-Peng Qi, Shu-An Li, Yong-Qing Huang, Guan-Cheng Xu, Guang-Xiang Liu, Ling-Yan Kong, Wei-Yin Sun,