Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1302450 | Inorganic Chemistry Communications | 2011 | 4 Pages |
Reactions between hexanuclear manganese pivalate with lanthanide salts (chlorides or nitrates), in the presence of potassium hydroxide, 2-pyridylmethanol and sodium azide leads to formation of a new family of hexaheteronuclear manganese–lanthanide clusters.
Graphical abstractReactions between hexanuclear manganese pivalate with lanthanide salts (chlorides or nitrates), in the presence of potassium hydroxide, 2-pyridylmethanol and sodium azide leads to formation of new family of hexaheteronuclear manganese–lanthanide clusters.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► An effective approach to access of new hexanuclear 3d-4f clusters. ► Weak antiferromagnetic intermolecular interactions. ► Molecular construction of manganese–lanthanide complexes with different nuclearity.