Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1302532 | Inorganic Chemistry Communications | 2011 | 4 Pages |
Two new Cd(II)-tetrazole coordination polymers with different auxiliary anions, namely [Cd10(ATZ)13(ac)2(H2O)2F5]•2H2O (1) and [Cd3(ATZ)4Cl2(C2H5OH)2] (2), were solvothermally synthesized and structurally characterized. Both compounds exhibit interesting three-dimensional Cd-ATZ frameworks, but their coordination networks are totally different and show distinct topologies.
Graphical abstractTwo new Cd-ATZ frameworks with different auxiliary anions exhibit distinct 12-nodal (3,4,5)-connected topology and 3-nodal (3,4)-connected topology, respectively.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► New Cd(II)-tetrazole coordination polymers with different auxiliary anions. ► Three-dimensional Cd-ATZ frameworks with distinct topologies. ► Anion-controlled versatility of coordination frameworks.