| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1302568 | Inorganic Chemistry Communications | 2011 | 4 Pages |
Hexanuclear [MnIII6O2(Hsalaox)6(MeOH)4(MeCO2)2]·4MeOH·2H2O (1) and polymeric [MnIII6O2(Hsalaox)6(MeOH)6(tp)]·12H2O (2) are prepared by the reaction of Mn2+, salicylamidoxime (H3salaox) and corresponding carboxylates (tp2− = terephthalate). Magnetic studies show that both complexes display slow magnetization relaxation.
Graphical abstractHexanuclear [Mn6O2(Hsalaox)6]2+ fragments can form discrete clusters and a terephthalate-bridged 1D chain, which display slow magnetization relaxation.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Salicylamidoxime as the ligand for polynuclear Mn6 complexes. ► Terephthalic acid as the bridging ligand for polymeric coordination compound. ► Novel 1D complex that contains hexanuclear Mn(III) as nodes. ► Slow relaxation of magnetization for two compounds has been observed. ► No obvious improvements in magnetism by changing Mn6 to 1D.
